还原胺化
转移加氢
甲酸
催化作用
化学
钴
胺化
硝基
一锅法合成
氢
有机化学
贵金属
无机化学
钌
烷基
出处
期刊:Chemsuschem
[Wiley]
日期:2017-04-11
卷期号:10 (9): 1892-1897
被引量:67
标识
DOI:10.1002/cssc.201700348
摘要
Abstract A new method was developed for the synthesis of secondary amines through the one‐pot reductive amination of carbonyl compounds with nitro compounds using formic acid as the hydrogen donor over a heterogeneous non‐noble‐metal catalyst (Co‐N x /C‐800‐AT, generated by the pyrolysis of the cobalt phthalocyanine/silica composite at 800°C under a N 2 atmosphere and subsequent etching by HF). Both nitrogen and cobalt were of considerable importance in the transfer hydrogenation reactions with formic acid.
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