表面改性
氢原子
功能群
分子
氢键
群(周期表)
化学
Atom(片上系统)
组合化学
有机化学
计算机科学
聚合物
物理化学
嵌入式系统
标识
DOI:10.1016/j.trechm.2022.04.003
摘要
Direct functionalization of C–H bonds is a powerful synthetic tool that unlocks tremendous opportunities for late-stage elaboration of complex molecules. Recent advances of a new strategy, merging radical-mediated functional group migration (FGM) with hydrogen atom transfer (HAT), have shown great potential for site-selective C(sp3)–H bond functionalization. Direct functionalization of C–H bonds is a powerful synthetic tool that unlocks tremendous opportunities for late-stage elaboration of complex molecules. Recent advances of a new strategy, merging radical-mediated functional group migration (FGM) with hydrogen atom transfer (HAT), have shown great potential for site-selective C(sp3)–H bond functionalization.
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