拉曼光谱
激发态
反对称关系
化学
共振(粒子物理)
动力学(音乐)
环己烷
谱线
分子物理学
国家(计算机科学)
乙烯
反应动力学
核磁共振
光化学
原子物理学
物理
分子
光学
量子力学
数学物理
有机化学
算法
计算机科学
声学
催化作用
作者
Huigang Wang,Bo Liu,Yanying Zhao,Xuming Zheng
摘要
Abstract A ‐ and B ‐band resonance Raman spectra were acquired for ethylene trithiocarbonate in cyclohexane solution. The results indicate that the S 3 state structural dynamics is mostly along vibrational motions of the CS stretch υ 11 , while the S 4 state one has motions mainly via the SCS symmetric stretch υ 18 , CS stretch υ 11 , and the HCH rock + SCS antisymmetric stretch υ14 reaction coordinates. The very different excited state structural dynamics were briefly discussed in terms of vibronic couplings using local symmetry point group. Copyright © 2009 John Wiley & Sons, Ltd.
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