Constructing a highly tough, durable, and renewable flexible filter by epitaxial growth of a glass fiber fabric for high flux and superefficient oil-water separation

The separation and purification of complex and stable stubborn oily sewage is extremely challenging. To respond to this challenge, we developed a powerful flexible filter with ultrahigh strength, durability, flux, separation efficiency, and a multiobjective separation function based on a universal epitaxial growth process of glass fiber fabric (Gf). The underwater oil contact angle (UOCA) of the silicate@Gf (MgSi@Gf) filter is 156.3°, so it can achieve both an ultrahigh permeation flux (5632.7 L·m-2·h-1) and oil-water separation efficiency (99.5%) under gravity (≈ 1 kPa) in purifying surfactant-stabilized emulsions, actual industrial oily sewage and mechanical cold rolling emulsions. The filter with a high tensile strength (66.5 MPa) and oil invasion pressure (4626 Pa) can withstand the impact of much sewage or intense water flow. The filter can tolerate extreme conditions and can maintain high separation performance in acid or alkaline (pH 1-13), high or low temperature (100 °C, 200 °C, -18 °C) conditions or natural salty waters such as seawater. The filter can remove methylene blue (MB) dye (99.8%) by filtration, and can be repeatedly and easily reconstructed (renewable advantage). The filter shows great potential for efficiently eliminating the hazards of contaminants in actual oily sewage and thus protect human health.