共聚物
聚烯烃
聚合物
单体
材料科学
高分子科学
高分子化学
化学工程
复合材料
工程类
图层(电子)
作者
Wei Xiong,Jiang Dai,Zhongzheng Cai,Jian‐Bo Zhu
出处
期刊:Polymer
[Elsevier]
日期:2023-11-20
卷期号:290: 126515-126515
被引量:4
标识
DOI:10.1016/j.polymer.2023.126515
摘要
Developing new chemically recyclable polymers provides an opportunity for establishing a circular plastic economy. However, it is still challenging to reconcile both polymer recyclability and material properties. Herein, we aimed to exploit copolymerization of 3-methyl-dithian-2-one (Me-DTO) and thiovalerolactone (TVL) to access chemically recyclable polythioesters with high-performance material properties. Adjusting the copolymer compositions allowed to modulate the thermal and mechanical properties of the resulting copolymers extensively. Ultimately, polyolefin-like mechanical properties was achieved for P[(Me-DTO)100-co-(TVL)900] (σB = 33.87 ± 4.79MPa and εB = 638 % ± 112 %). These copolymers were capable of depolymerizing into their monomers in solution or bulk efficiently with high yields of >95 %, thus establishing their circular life cycle.
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