Flash Reforming Pyrogenic Carbon to Graphene for Boosting Advanced Oxidation Reaction

Abstract Biomass‐derived pyrogenic carbon is attractive for advanced oxidation processes (AOPs); however, its amorphous structure limits its activation efficiency. Graphene with highly conjugated π structure possesses superior electron transport ability and thus high usefulness. However, bygone strategies are scarcely effective for reforming pyrogenic carbon to graphene. Herein, for the first time, a state‐of‐the‐art flash Joule heating (FJH) technique is showcased for reforming pyrogenic carbon to 2–5‐layer graphene. FJH current‐induced ultrahigh temperature and stress field realize instantaneous (≈10 s) regeneration of pyrogenic carbon via synchronization actions of carbonization, graphitization, and exfoliation. Meanwhile, volatilization of doped N atoms accelerates graphitization but has less of an effect on graphene configuration. Accordingly, tuned oxygen groups at the graphene edge boost peroxydisulfate (PDS) adsorption for finer initiating activation. Subsequently, 2D graphene with excellent electron utilization rate strengthens hydroxyl radical and direct electron transfer pathways in activating PDS for sulfamethoxazole (SMX) degradation. Impressively, the SMX degradation efficiency by fabricated graphene raises ≈8.9‐fold as compared with pristine pyrogenic carbon. Additionally, fabricated graphene is more efficient in PDS activation than commercial metal catalysts. Undoubtedly, this study realizes effective transformation of pyrogenic carbon to graphene for highly efficient metal‐free carbocatalyst.