聚酰胺
渗透
选择性
树枝状大分子
膜
质子化
化学工程
纳滤
图层(电子)
化学
界面聚合
多孔性
材料科学
聚合
胺气处理
高分子化学
离子
聚合物
有机化学
单体
生物化学
工程类
催化作用
作者
Bingbing Yuan,Mengxue Wang,Menghan Wu,Dongxiao Yang,Kaili Zhang,Siheng Zhao,Yuhang Zhang,Ping Hu,You Meng,Shengchao Zhao,Kuo Chen,Xiaozhuan Zhang,Juhui Jiang,Xiangdong Lou,Q. Jason Niu
标识
DOI:10.1016/j.memsci.2024.122743
摘要
Nanofiltration membrane with fine-tuned pore structure and inner charge can achieve the efficient extraction of Li resource from Salt Lake. Herein, we synthesized three water-soluble dendrimers with 128, 256, and 512-aromatic amine groups that enable to be protonated to show positive charge. Protonated dendrimer porous intermediate layer, thus can be designed and fabricated via diazotization-coupling reaction, which imparts interfacial polymerization polyamide dense layer with optimized screening pore structure and decreased inner negative charge. Enhanced water/salt permeance was obtained due to the formation of nanostripe structure and thinner thickness of separation layer, as high as 360.87 kg m−2 h−1 MPa−1 for 2000 ppm LiCl. Furthermore, the asymmetric polyamide nanofilm with decreased negative charge density provided 11.52 times of Li+/Mg2+ separation selectivity compared to the pristine counterparts. For example, the PSF-160A-PA membrane exhibited a Li+/Mg2+ selectivity of 45.8. Higher cut-off lines between water permeance and Li+/Mg2+ separation selectivity were achieved, while achieving higher Li purity and Li recovery was observed, which was better than some of literature-reported membranes. This work presents a scalable strategy to fine-tune the structural feature of intermediate layer, then form defect-free polyamide nanofilm for accurate ion sieving.
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