异构化
烯丙基重排
催化作用
钌
氧化还原
化学
分子内力
光化学
有机化学
作者
Xiaozhong Chen,Xingyou Han,Jing Xu,Junjie Yu,Chen Chen,Jiazhi Yang,Feng Li
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2022-12-29
卷期号:5 (1): 700-710
被引量:4
标识
DOI:10.1021/acsapm.2c01668
摘要
A metallopolymer, Ru(p-cymene)@poly(2,2′-BiBzlm), which is synthesized by the incorporation of [Ru(p-cymene)Cl]2 into poly(bibenzimidazoles), was proven to be a general and efficient catalyst for the redox isomerization of allylic alcohols to ketones. Mechanistic experiments showed that this reaction is in agreement with an intramolecular hydrogen shift. This catalyst was also applied to the gram-scale synthesis of a biologically active molecule. Furthermore, this catalyst could be recycled five times without an obvious decrease in activity.
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