化学
紫外线
硼
Crystal(编程语言)
结晶学
晶体结构
离子
紫外线辐射
金属
光电子学
材料科学
计算机科学
放射化学
有机化学
程序设计语言
作者
Shuzhao Huang,Liang Zhu,Ivan A. Kruglov,Yun Yang,Zhihua Yang,Shilie Pan
标识
DOI:10.1021/acs.inorgchem.3c00519
摘要
Borates and fluorooxoborates are advanced optical materials with great potential applications in the ultraviolet (UV) and deep ultraviolet (DUV) regions. Herein, two new UV optical crystals K6B12O19F4 and K12B28O48 were synthesized. Among them, K6B12O19F4 has a rare disorder of BO3 and BO4 units, which is the first time this disordered type has been found in fluorooxoborates. In this paper, the properties of K6B12O19F4 and K12B28O48 were tested and calculated, and their crystal structures and structural evolution were carefully analyzed. In addition, the effects of metal cations size and F ions on the crystal structure were analyzed. This research enriches the structural chemistry of borates and fluorooxoborates, and provides experience for the design of new UV optical crystals.
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