钯
锡
过氧化氢
催化作用
化学
氢
水溶液
选择性
氧气
无机化学
材料科学
有机化学
作者
Simon J. Freakley,Qian He,Jonathan H. Harrhy,Li Lu,David A. Crole,David Morgan,Edwin N. Ntainjua,Jennifer K. Edwards,Albert F. Carley,Albina Y. Borisevich,Christopher J. Kiely,Graham J. Hutchings
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:2016-02-25
卷期号:351 (6276): 965-968
被引量:502
标识
DOI:10.1126/science.aad5705
摘要
Direct hydrogen peroxide synthesis Hydrogen peroxide is synthesized industrially without direct contact of hydrogen and oxygen in order to achieve high concentrations. For many applications, only dilute aqueous solutions are needed. Freakley et al. report an improvement in the direct synthesis of hydrogen peroxide over using palladium-tin alloys. This catalyst still achieves selectivities of >95%, like palladium-gold alloys, but is cheaper and can suppress reactions that decompose the product. Science , this issue p. 965
科研通智能强力驱动
Strongly Powered by AbleSci AI