胶粘剂
磷酸二氢铵
磷酸铵
材料科学
固化(化学)
环境友好型
耐水性
磷酸盐
缩聚物
化学工程
铵
复合材料
制浆造纸工业
高分子化学
化学
有机化学
原材料
聚合物
工程类
生物
图层(电子)
肥料
生态学
作者
Zhongyuan Zhao,Shin Hayashi,Wei Xu,Zhihui Wu,Soichi Tanaka,Shijing Sun,Min Zhang,Kozo Kanayama,Kenji Umemura
出处
期刊:Polymers
[Multidisciplinary Digital Publishing Institute]
日期:2018-11-12
卷期号:10 (11): 1251-1251
被引量:46
标识
DOI:10.3390/polym10111251
摘要
Development of a bio-based wood adhesive is a significant goal for several wood-based material industries. In this study, a novel adhesive based upon sucrose and ammonium dihydrogen phosphate (ADP) was formulated in hopes of furthering this industrial goal through realization of a sustainable adhesive with mechanical properties and water resistance comparable to the synthetic resins used today. Finished particleboards exhibited excellent mechanical properties and water resistance at the revealed optimal adhesive conditions. In fact, the board properties fulfilled in principle the requirements of JIS A 5908 18 type standard, however this occured at production conditions for the actual state of development as reported here, which are still different to usual industrial conditions. Thermal analysis revealed addition of ADP resulted in decreases to the thermal thresholds associated with degradation and curing of sucrose. Spectral results of FT-IR elucidated that furanic ring chemistry was involved during adhesive curing. A possible polycondensation reaction pathway was proposed from this data in an attempt to explain why the adhesive exhibited such favorable bonding properties.
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