膜
材料科学
电解
电化学
化学工程
离子交换
电解水
聚合物
电导率
极限抗拉强度
肿胀 的
耐久性
高分子化学
复合材料
化学
电极
离子
有机化学
工程类
物理化学
电解质
生物化学
作者
Chuan Hu,Ju Yeon Lee,Young Jun Lee,Se Hak Kim,Hyewon Hwang,Kyoung-seok Yoon,Chang-dae Park,So Young Lee,Young Moo Lee
标识
DOI:10.1016/j.nxener.2023.100044
摘要
Low-cost anion exchange membrane water electrolysis (AEMWE) is an attractive technology to address global energy shortages and environmental issues. However, AEMWE remains far from industrial application because of its poor performance and durability, issues that are associated with a lack of qualified anion exchange membranes (AEMs). Here, we describe the use of reinforced membrane technology in AEMs to prepare robust membranes, and systematically explore the effect of support-layer and polymer-membrane thicknesses on water electrolysis. Due to the excellent electrochemical properties of filled poly(dibenzyl-co-terphenyl piperidinium) polymers, the prepared reinforced membrane displays outstanding mechanical properties, with a tensile strength > 112 MPa, and an elongation at break > 84 %, conductivity (96.3 mS cm−1), and dimensional stability (swelling ratio < 50 % at 80 °C). More importantly, AEMWE based on the reinforced membrane simultaneously can achieve an exceptional current density of 4.86 A cm−2@2.0 V and in-situ durability under 1 and 2 A cm−2 at 60 °C for 1000 h with a voltage decay rate of 0.02 mV h−1 and 0.1 mV h−1, respectively. These findings provide insight into the development of AEMWEs using reinforced membranes.
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