催化作用
聚合
开环聚合
醇盐
单体
丙交酯
聚酯纤维
高分子化学
戒指(化学)
组合化学
化学
缩聚物
材料科学
有机化学
化学工程
聚合物
工程类
作者
Ze Kan,Wenlong Luo,Tong Shi,Chuanzhi Wei,Binghao Han,Dejuan Zheng,Shaofeng Liu
标识
DOI:10.3389/fchem.2018.00547
摘要
Ring-opening polymerization (ROP) of cyclic esters/lactones by efficient catalysts is a powerful method for synthesis of biodegradable and biocompatible polyesters with well-defined structures. To develop catalytic systems that are fast, selective and controlled is a persistent effort of chemists. In this contribution, we report a binary urea/alkoxide catalytic system that could catalyze ROP of rac-LA in a fast (over 90% conversion within 1-2 min), stereoselective (Pi up to 0.93) and controlled manner, indicated by narrow MW distributions, linear relationship between the monomer conversions and Mns, end-group fidelity, and chain extension experiments. Remarkably, the catalytic system described here is simple, easily prepared, and structurally tunable and thus has versatile catalytic performances.
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