阳极
插层(化学)
材料科学
电化学
同步加速器
相(物质)
电极
混合材料
钠离子电池
化学工程
离子
钠
纳米技术
无机化学
化学
物理化学
光学
法拉第效率
冶金
工程类
有机化学
物理
作者
Chunjin Wu,Weibo Hua,Zheng Zhang,Benhe Zhong,Zuguang Yang,Guilin Feng,Wei Xiang,Zhenguo Wu,Xiaodong Guo
标识
DOI:10.1002/advs.201800519
摘要
A novel complementary approach for promising anode materials is proposed. Sodium titanates with layered Na2Ti3O7 and tunnel Na2Ti6O13 hybrid structure are presented, fabricated, and characterized. The hybrid sample exhibits excellent cycling stability and superior rate performance by the inhibition of layered phase transformation and synergetic effect. The structural evolution, reaction mechanism, and reaction dynamics of hybrid electrodes during the sodium insertion/desertion process are carefully investigated. In situ synchrotron X-ray powder diffraction (SXRD) characterization is performed and the result indicates that Na+ inserts into tunnel structure with occurring solid solution reaction and intercalates into Na2Ti3O7 structure with appearing a phase transition in a low voltage. The reaction dynamics reveals that sodium ion diffusion of tunnel Na2Ti6O13 is faster than that of layered Na2Ti3O7. The synergetic complementary properties are significantly conductive to enhance electrochemical behavior of hybrid structure. This study provides a promising candidate anode for advanced sodium ion batteries (SIBs).
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