立体中心
手性(物理)
轴手性
金属
酰胺
配体(生物化学)
对映体
化学
化学物理
旋转(数学)
材料科学
结晶学
立体化学
几何学
物理
对映选择合成
有机化学
手征对称性
量子力学
催化作用
受体
数学
生物化学
夸克
Nambu–Jona Lasinio模型
作者
Chunmiao Ma,Qingyun Cao,Lu Yu,Ma Zhao,Quan Gan
标识
DOI:10.1002/anie.202410731
摘要
A series of metal‐organic cages featuring two stereogenic elements, in terms of the twisting of amide moieties within the ligand backbones and the rotation of diazaanthracene segments along the ligand ridges, were exploited. These two chiral components are correlative and serve as relays for transmitting chirality information between the internal and external cages. The chirality information induced by a chiral guest inside the cage cavity can pass through the cage framework and influence the orientation of the diazaanthracene segments on the periphery of the cage. In turn, the chirality of a stereogenic center within the diazaanthracene segments can transfer back into the cavity, enabling discrimination of enantiomeric guests.
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