氧化还原
催化作用
材料科学
铬
铟
化学工程
流动电池
催化循环
吸附
电池(电)
储能
纳米技术
电极
化学
冶金
电解质
有机化学
热力学
功率(物理)
物理
物理化学
工程类
作者
Yingchun Niu,Yinping Liu,Tianhang Zhou,Chao Guo,Guorong Wu,Wenjie Lv,Ali Heydari,Bo Peng,Xu Chen,Quan Xu
标识
DOI:10.1016/j.gee.2024.04.005
摘要
Iron-chromium flow batteries (ICRFBs) have emerged as an ideal large-scale energy storage device with broad application prospects in recent years. Enhancement of the Cr3+/Cr2+ redox reaction activity and inhibition of the hydrogen evolution side reaction (HER) are essential for the development of ICRFBs and require a novel catalyst design. However, elucidating the underlying mechanisms for modulating catalyst behaviors remains an unresolved challenge. Here, we show a novel precisely controlled preparation of a novel thermal-treated carbon cloth electrode with a uniform deposit of low-cost indium catalyst particles. The density functional theory analysis reveals the In catalyst has a significant adsorption effect on the reactants and improves the redox reaction activity of Cr3+/Cr2+. Moreover, H+ is more easily absorbed on the surface of the catalyst with a high migration energy barrier, thereby inhibiting the occurrence of HER. The assembled ICRFBs have an energy efficiency of 85.23% at 140 mA/cm2, and this method minimizes the electrodeposition process and cleans the last obstacle for industry long cycle operation requirements. The ICRFBs exhibit exceptional long-term stability with an energy efficiency decay rate of 0.011% per cycle at 1000 cycles, the lowest ICRFBs reported so far. Therefore, this study provides a promising strategy for developing ICRFBs with low costs and long cycle life.
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