Magnéli phase titanium sub-oxides synthesis, fabrication and its application for environmental remediation: Current status and prospect

Sub-stoichiometric titanium oxide, also called titanium suboxides (TSO), had been a focus of research for many decades with a chemical composition of TinO2n-1 (n ≥ 1). It has a unique oxygen-deficient crystal structure which provides it an outstanding electrical conductivity and high corrosion resistance similar to ceramic materials. High electrical conductivity and ability to sustain in adverse media make these phases a point of attention for researchers in energy storage and environmental remediation applications. The Magnéli phase-based reactive electroconductive membranes (REM) and electrodes have demonstrated the electrochemical oxidation of pollutants in the water in flow-through and flow by configuration. Additionally, it has also shown its potential for visible light photochemical degradation as well. This review attempts to summarize state of the art in various Magnéli phases materials synthesis routes and their electrochemical and photochemical ability for environmental application. The manuscript introduces the Magnéli phase, its crystal structure, and catalytic properties, followed by the recent development in synthesis methods from diverse titanium sources, notably TiO2 through thermal reduction. The various fabrication methods for Magnéli phase-base REMs and electrodes have also been summarized. Furthermore, the article discussed the environmental remediations via electrochemical and photochemical advanced oxidation processes. Additionally, the hybrid technology with REMs and electrodes is used to counter membrane biofouling and develop electrochemical sensing devices for the pollutants. The Magnéli phase materials have a bright future for both electrochemical and photochemical advanced oxidation of emerging contaminants in water and wastewater treatment.