High‐performance anode materials for Na‐ion batteries

Abstract Na‐ion batteries are considered a promising alternative to Li‐ion batteries for large‐scale energy storage systems due to their low cost and the natural abundance of Na resource. Great effort is making worldwide to develop high‐performance electrode materials for Na‐ion batteries, which is critical for Na‐ion batteries. This review provides a comprehensive overview of anode materials for Na‐ion batteries based on Na‐storage mechanism: insertion‐based materials, alloy‐based materials, conversion‐based materials and organic composites. And we summarize the Na‐storage mechanism of those anode materials and discuss their failure mechanism. Furthermore, the problems and challenges associated with those anodes are pointed out, and feasible strategies are proposed for designing high‐performance anode materials. According to the current state of research, the search for suitable anode materials for Na‐ion batteries is still challenging although substantial progress has been achieved. Nevertheless, we believe that high‐performance Na‐ion batteries would be promising for practical applications in large‐scale energy storage systems in the near future.