А. С. Газизов,E. A. Kuznetsova,Aidar Z. Kamaletdinov,А. В. Смолобочкин,О. А. Лодочникова,D. P. Gerasimova,А. Р. Бурилов,М. А. Пудовик
出处
期刊：Organic chemistry frontiers [The Royal Society of Chemistry] 日期：2023-01-01卷期号：10 (18): 4550-4558
标识
DOI：10.1039/d3qo00580a
摘要
Contrary to chemical intuition, electron-donating groups decrease the nucleophilicity of the double bond in imidazolin-2-ones, switching their reactivity from “enamide” to “base”. Enamide reactivity can be recovered by a careful choice of the catalyst and solvent.
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