Structure, orientation, and dynamics of per- and polyfluoroalkyl substances (PFAS) surfactants at the air-water interface: A molecular-level insights

Understanding the intricate molecular-level details of toxic per- and polyfluoroalkyl substances (PFAS) partitioning to the air-water interface holds paramount importance in evaluating their fate and transport, as well as for finding safer alternatives for various applications, including aqueous film forming foams. The behavior of these substances at interfaces strongly depends on molecular architecture, chemistry, and concentration, which define molecular packing, self-assembly, interfacial diffusion, and the surface tension.