三乙胺
催化作用
劈理(地质)
键裂
丙胺
化学
光催化
光化学
药物化学
有机化学
材料科学
胺气处理
断裂(地质)
复合材料
作者
Jianxin Zhai,Baowen Zhou,Haihong Wu,Shuaiqiang Jia,Mengen Chu,Shitao Han,Wei Xia,Mingyuan He,Buxing Han
出处
期刊:Chemsuschem
[Wiley]
日期:2022-07-12
卷期号:15 (18)
被引量:3
标识
DOI:10.1002/cssc.202201119
摘要
Abstract Development of a new and green strategy for C(sp 3 )−N bond cleavage is very interesting. Herein, photocatalytic cleavage of the C(sp 3 )−N bond of trialkylamines was achieved, with concurrent formation of dialkylamines and olefins. It was found that a rationally designed 2D‐Bi 2 WO 6 @1D‐LaPO 4 heterostructure was very efficient for the reaction due to its high light collection efficiency and unique catalytic properties. The strategy could be used for different trialkylamines, including triethylamine, tri‐ n ‐propylamine, and ethyl‐di‐isopropylamine. The mechanistic investigation indicated that the catalyst with heterostructure was not only favorable for charge carrier separation but also rendered excited electrons with high reduction capacity. This work opens a way for C(sp 3 )−N bond cleavage of trialkylamines.
科研通智能强力驱动
Strongly Powered by AbleSci AI