材料科学
钴
超级电容器
双金属片
沸石咪唑盐骨架
咪唑酯
硫化钴
氧化钴
电极
三元运算
金属有机骨架
氧化物
无机化学
电化学
硫化物
化学工程
金属
石墨烯
纳米技术
冶金
化学
有机化学
程序设计语言
物理化学
吸附
工程类
计算机科学
作者
Aya M. Mohamed,Mohamed Ramadan,Nageh K. Allam
标识
DOI:10.1016/j.est.2020.102195
摘要
Strategies to overcome the intrinsic limitations of zeolitic imidazolate frameworks ZIF-67 for use as catalytically active electrode materials for electrochemical supercapacitor devices have been reviewed and discussed. Despite the achieved enhancements so far, there are still various challenges that need to be tackled, including the limited rate capability and charging voltage window of the ZIF-67 material. In this regard, a wide range of ZIF-67-derived materials have been reviewed and discussed, including: 1) Porous carbons, metal/non-metal-doped porous carbons, and carbon-carbon composites. 2) Cobalt oxide nanostructures, cobalt oxide-based composites, bimetallic ternary metal oxides, and iron and manganese oxides. 3) Cobalt sulfide nanostructures, bimetallic ternary metal sulfides, and metal sulfide composites. 4) Cobalt sulfide, and cobalt phosphides. Moreover, defect engineering and doping strategies were discussed as possible strategies to improve the electrochemical performance of ZIF-67-derived metal oxides. Further, ZIF-67-derived layer double hydroxides (LDHs) and selenides were discussed. Finally, the remaining challenges and future perspectives have been highlighted.
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