生物炭
吸附
磷酸盐
化学工程
基质(化学分析)
无机化学
水溶液中的金属离子
腐植酸
金属
化学
核化学
有机化学
色谱法
肥料
热解
工程类
作者
Haoyu Luo,Yi Wan,Yuhao Cai,Zhi Dang,Hua Yin
出处
期刊:ACS ES&T engineering
[American Chemical Society]
日期:2022-07-25
卷期号:2 (12): 2254-2265
被引量:21
标识
DOI:10.1021/acsestengg.2c00212
摘要
In phosphate adsorption, the interaction between MgO and the carbon network in Mg-biochar is an overlooked factor that contributes to active MgO facet generation for enhancing phosphate adsorption. However, the complex water matrix adsorption mechanism underlying the adaptability of MgO-biochar and enhanced phosphate adsorption are not fully studied. Herein, Mg-stirred leaf biochar (Mg-SLBC) was prepared by the Mg-stirring modification method. Mg-SLBC possessed the highest adsorption capacity (79.28 mg g–1) to phosphate among the adsorbents. In addition, Mg-SLBC had a good performance for phosphate adsorption in a complex water matrix. Phosphate adsorption by Mg-SLBC was not affected by Cl–, NO3–, SO42–, humic acid, metal ions, and Ca2+ but was inhibited by Mg2+ and HCO3–. For long-term adsorption, Mg-SLBC could constantly adsorb phosphate to avoid phosphate accumulation (<2 mg L–1). Meanwhile, phosphate adsorption by Mg-SLBC was a spontaneous process (ΔG, −6.884 kJ mol–1), which was dominated by inner-sphere complexation. Owing to high combination between MgO and the carbon network, there were more active MgO facets (e.g., (1 1 0) and (2 0 0)) to induce stronger unbalanced electron distribution in Mg-SLBC. Thereby, Mg-SLBC, with high adsorption capacity and adaptability, could effectively adsorb phosphate in a complex water matrix.
科研通智能强力驱动
Strongly Powered by AbleSci AI