3D printing MXene‐based electrodes for supercapacitors

3D printing, as an advanced and promising strategy for processing electrode for energy storage devices, such as supercapacitors and batteries, has garnered considerable interest in recent decades. The interest in 3D printed electrodes stems from its exceptional performance and manufacturing features, including customized sizes and shapes and the layer-by-layer processing principle, etc., especially integrating with MXene which allows the manufacturing of electrodes from different raw materials and possessing desired electrochemical properties. Herculean challenges, such as material compatibility of the printing inks, nondurable interfacial or bulk mechanical strength of the printed electrodes, and sometimes the low capacitance, lead to inferior electrochemical performance and hinder the practical applications of this promising technology. In this review, we firstly summarize the representative 3D printing methods, then, review the MXene-based 3D printing electrodes made from different materials, and last, provide electrochemical performance of 3D printing MXene-based electrodes for supercapacitors. Furthermore, based on a summary on the recent progress, an outlook on these promising electrodes for sustainable energy devices is provided. We anticipate that this review could provide some insights into overcoming the challenges and achieving more remarkable electrochemical performance of 3D printing supercapacitor electrodes and offer perspectives in the future for emerging energy devices.