催化作用
联氨(抗抑郁剂)
分解
混合(物理)
同种类的
贵金属
无机化学
铜
大规模运输
材料科学
化学
化学工程
冶金
热力学
有机化学
色谱法
工程类
物理
量子力学
标识
DOI:10.1016/j.apcatb.2021.120569
摘要
The results of two previously published articles about the catalytic decomposition of hydrous hydrazine were analyzed. Experimentally it was shown that Ni0.5Cu0.5/CeO2 catalyst is more active than Ni/CeO2. However, the measured impact of external mass transport on the observed decomposition rate contradicts heterogeneous catalysis's fundamental chemical engineering principles. The observed deviation could be described only by the copper-induced homogeneous reaction.
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